副教授/博士/硕士生导师
招生领域（方向）：资源与环境
主要研究方向：清洁催化材料研究方向 化学反应机理
邮箱：jyzhao1981@163.com
通讯地址：江苏省 南京市 江宁区弘景大道3601号 环境科学学院 211171
学术简历：
参与国家自然科学基金项目3项，主持完成江苏省高校自然科学基金2项，横向项目2项。发表SCI论文二十余篇，授权发明专利4项，实用新型专利数十项。获得南京市自然科学优秀论文奖１项。指导学生发表一作SCI一区论文１篇，发明专利１项，实用新型专利12项，外观专利1项。指导学生获得2021“挑战杯”全国竞赛江苏省决赛一等奖、2022年江苏省优秀本科毕业论文三等奖。
项目：
1. 江苏省高等学校自然科学研究面上项目，19KJB150034，非金属路易斯酸碱催化C-H和N-H键活化及功能化反应的机理研究，2019/09-2022/08，已结项，主持；
2. mRNA递送系统的脂质化合物开发，南京澄实生物医药科技有限公司，横向项目，2023.07-2026.07，在研，主持。
3. 国家自然科学基金面上项目，过氧化亚硝酰诱导的线粒体自噬过程的精准跟踪及调控响应研究，2022.08-2027.08，在研，参与。
4. 国家自然科学基金-国际（地区）合作与交流项目，21361140376，发展用于非金属催化氢化反应的空间受阻路易斯酸碱对，2014/01-2016/12，已结项，参与。
5. 国家自然科学基金青年项目，21401106，寿命成像型锌离子双光子荧光探针的构筑与活体应用，2015/01-2017/12，已结项，参与。
论文：
1. Pan Du, Ling Han, Xue Zhang, Qin Yu, Li Li, and Jiyang Zhao*. Mechanistic Insights into the Methylation and Formylation of Amines with CO2: Exploring Diverse CO2 Activation Models. The Journal of Organic Chemistry, 2025, 90 (8), 3011-3021.
2. Yang, Jingjing; Zhao, Jiyang; Xie, Rui; Wu, Cheng; Huang, Fang.Constructing polyfunctional reactive dyes for printing of cotton fabrics with ultra-high fixation and ultra-low staining on the white ground. Cellulose,2025, 32, 1917–1936.
3. Zhang Y, Zhao J, Cheng J, Wang X, Wang H, Shao Y, Mao X, He X. Bromine-mediated strategy endows efficient electrochemical oxidation of amine to nitrile. Chem Commun (Camb). 2024 Feb 22;60(17):2369-2372.
4. Ma D, Ma X, Xie M, Liu X, Zai J, Qian X, Wang X, Zhao J, Pan Z, Liang X, Zhang Y. Phase-Selective Synthesis of Cobalt Sulfide Heterostructure Catalysts as Efficient Counter Electrodes in Dye-Sensitized Solar Cells. Chempluschem.2023 Jul;88(7):e202300191.
5. Pan Du, Xinyue Liu, Xinyi Dong, Nianyang Li, Rui Liu, Li Li, Jiyang Zhao*. Theoretical study of reductive CO2 functionalization with amines and phenylsilanes: what kind of solvents can be used as catalysts?Catal. Sci. Technol., 2023, 13, 5333-5344.
6. Yuchi Zhang, Xin He, Xiaofeng Wang, Jiyang Zhao, Jiongjia Cheng, Zhaorui Pan, Bo Zheng, Shaoxian Liu, Dui Ma, and Hai-Ying Wang. Selective Electrochemical Oxidation of p-Xylylene Glycol Coupled with the Hydrogen Evolution Reaction via a Continuous Flow Strategy. ACS Sustainable Chemistry & Engineering202311 (32), 11947-11954.
7. Du P, Yin Y, Shi D, Mao K, Yu Q, Zhao J*. Metal-Free Phosphination and Continued Functionalization of Pyridine: A Theoretical Study. Molecules. 2022,27(17):5694.
8. Jiyang Zhao*, Shaoxian Liu, Shanshan Liu, Wenwen Ding, Sijia Liu, Yao Chen, and Pan Du. A Theoretical Study on the Borane-Catalyzed Reductive Amination of Aniline and Benzaldehyde with Dihydrogen: The Origins of Chemoselectivity. The Journal of Organic Chemistry202287 (2), 1194-1207.
9. Xiao-feng Wang, Ji-yang Zhao, Meng-Qi Jia, Xiu Du Zhang, Xiao-bing Xu, Jiong-jia Cheng, Ying Wang, Guang-Xiang Liu, Kai Chen. Study on the structure regulation and electrochemical properties of imidazole-based MOFs by small molecules. Journal of Solid State Chemistry, 2022, 316, 123528,
10. Pan Du, Jiyang Zhao*, Shanshan Liu and Zhen Yue. Insights into the nucleophilic substitution of pyridine at an unsaturated carbon center. RSC Adv., 2021, 11, 24238-24246.
11. ZhenYue, Jiyang Zhao*, Pan Du, and Guang-Xiang Liu* Insightsinto Naturally Occurring Compound Catalyzed Formylation and Methylation Reactions of Amines with CO2: The Origins of Chemoselectivity. ACS Sustainable Chem. Eng.2020, 8, 32, 11967–11976.
12. X. R. Li, J. L. Wei, Q. Li, S. S. Zheng, Y. X. Xu, P. Du, C. Y. Chen, J. Y. Zhao, H. G. Xue, Q. Xu, H. Pang, Nitrogen-Doped Cobalt Oxide Nanostructures Derived from Cobalt–Alanine Complexes for High-Performance Oxygen Evolution Reactions. Adv. Funct. Mater.2018, 28, 1800886.
13. PanDu, Jiyang Zhao*. Densityfunctional theory mechanistic study of boron-catalyzed N-alkylation of amines with formic acid: formic acid activation via silylation reaction. Chem. Asian J., 2018, 13(6),701-709.
14. JiyangZhao, Shuhua Li*. Charge-transfer-induced para-selectivesp2 C–H bond activation of arenes by use of a hypervalentiodine compound: a theoretical study. J. Org. Chem., 2017, 82 (6), 2984–2991.
15. Jiyang Zhao, GuoqiangWang, Shuhua Li*. An insightinto the Lewis acid-catalyzed intramolecular aminocyanation and oxycyanationof alkenes: a concerted or stepwise mechanism. Chem. Comm., 2015, 51, 15450–15453.
16. PanDu, Jiyang Zhao*. ComparativeDFT study of metal-free Lewis acid-catalyzed C–H and N–H silylation of (hetero)arenes: mechanistic studies and expansion of catalyst and substratescope. RSC Adv., 2019, 9, 37675-37685.
17. JiyangZhao, Guoqiang Wang, Shuhua Li*. Mechanisticinsights into the full hydrogenation of 2,6-substituted pyridine catalyzed bythe Lewis acid C6F5(CH2)2B(C6F5)2. DaltonTrans., 2015, 44, 9200–9208.
18. SureshMummadi, Daniel K. Unruh, Jiyang Zhao, Shuhua Li, and Clemens Krempner*. “Inverse” frustrated lewis pairs–activation ofdihydrogen with organosuperbases and moderate to weak lewis acids. J.Am. Chem. Soc., 2016, 138 (10), 3286–3289.
19. GuoqiangWang, Honglin Zhang, Jiyang Zhao, Wei Li, Jia Cao, Dr. Chengjian Zhu, Shuhua Li. Homolytic cleavage of a B−B bond by the cooperative catalysis of two Lewis bases: computational design and experimental verification. Angew. Chem. Int. Ed., 2016, 55, 5985-5989.
专利：
1.赵继阳 一种硼烷催化的对称型醚的合成方法ZL202110404399.X(发明专利)
2.赵继阳 一种甲基胺的制备方法ZL202010951702.3(发明专利)
3.赵继阳 一种用于芳香胺硅烷基化反应催化剂 ZL 2018 1 1294337.2 (发明专利)
4. 赵继阳 一种纤维棉酸沥滤处理的方法及装置 CN108793776B(发明专利)
获奖：
1. 乐振，2021“挑战杯”全国大学生课外学术科技作品竞赛江苏省决赛一等奖。（指导教师）
2. 乐振，2022年江苏省优秀本科毕业论文三等奖（指导教师）
3. 刘珊珊，姜依杰 严洲韬，2021年第二届全国大学生化学实验创新设计大赛华东赛区三等奖（指导教师）
4. 赵继阳，路易斯酸催化烯烃分子内加成X–CN (X=N, O)键的反应机理：协同还是分步？南京市第十二届自然科学优秀学术论文，优秀奖。
